Hammett Analysis of Photodecarbonylation in Crystalline 1,3-Diarylacetones
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https://figshare.com/articles/dataset/Hammett_Analysis_of_Photodecarbonylation_in_Crystalline_1_3_Diarylacetones/3302581
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资源简介：
The relative quantum yields and chemical efficiencies of crystalline p,p‘-disubstituted 1,3-diphenyl-2-propanones with 4-MeO, 4-Me, 4-F, 4-CF3,
and 3,4-diMeO groups were determined by parallel irradiation of polycrystalline samples. Variations in quantum yields that span a factor of
4 are analyzed in terms of the effects of substituents on the stability of the benzylic radical. All solid-state reactions proceeded with 100%
chemoselectivity and in >95% chemical yield.
创建时间：
2016-05-06
