Use of Calix[4]arenes in the Redox Chemistry of Lanthanides: the Reduction of Dinitrogen by a Calix[4]arene−Samarium Complex
收藏NIAID Data Ecosystem2026-03-06 收录
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The synthesis and structural characterization of a samarium−dinitrogen complex supported by a calix[4]arene ligand in which the N−N bond distance has been stretched to 1.611(16) Å are described. The central μ3-η2:η2:η2-hydrazido tetraanion formed is bonded to three SmIII centers with an overall butterfly-type arrangement.
创建时间:
2016-06-03



