Synthesis of Bi2S3 thin films based on pulse-plating bismuth nanocrystallines and its photoelectrochemical properties

The solubility of Bi3+ in aqueous solution is an important factor that
limits the fabrication of high quality Bi2S3 thin films. In order to find
a low–cost method to manufacture high quality Bi2S3 thin films, we are
reporting the preparation of the Bi2S3 thin films based on pulse-plating
method in this paper for the first time. The nano-bismuth particles were
obtained by electroplating on fluorine doped SnO2 (FTO) coated conducting
glass substrates with saturated bismuth potassium citrate solution as the
electroplating bath, and then it was put into a muffle furnace to oxidize.
Finally, the thin films depositing on FTO glass substrates were put into
the thioacetamide solution for vulcanization. In the end, the Bi2S3 thin
films were successfully prepared on FTO glass substrates. Different
characterization techniques were used to characterize the structure,
morphology and photoelectrochemical properties of the prepared thin films.
The test results revealed that we used this method can synthesize the high
quality of Bi2S3 thin films, thus the Bi2S3 materials synthesized through
this method are promising candidates in photoelectrochemical application.