Platinum(II)-Catalyzed Ethylene Hydrophenylation: Switching Selectivity between Alkyl- and Vinylbenzene Production
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https://figshare.com/articles/dataset/Platinum_II_Catalyzed_Ethylene_Hydrophenylation_Switching_Selectivity_between_Alkyl_and_Vinylbenzene_Production/2416108
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资源简介：
The
series of PtII complexes [(xbpy)Pt(Ph)(THF)][BAr′4] (xbpy =4,4′-X-2,2′-bipyridyl, X
= OMe, tBu, H, Br, CO2Et, NO2; Ar′
= 3,5-bis(trifluoromethyl)phenyl) are catalyst precursors for ethylene
hydrophenylation. The bipyridyl substituent provides a tunable switch
for catalyst selectivity that also has significant influence on catalyst
activity and longevity. Less electron donating 4,4′-substituents
increase the propensity toward styrene formation over ethylbenzene.
创建时间：
2013-05-13
