Zinc Hydride-Catalyzed Hydrofuntionalization of Ketones
收藏NIAID Data Ecosystem2026-03-11 收录
下载链接：
https://figshare.com/articles/dataset/Zinc_Hydride-Catalyzed_Hydrofuntionalization_of_Ketones/12855136
下载链接
链接失效反馈官方服务：
资源简介：
Three new dimeric bis-guanidinate
zinc(II) alkyl, halide, and hydride
complexes [LZnEt]2 (1), [LZnI]2 (2) and [LZnH]2 (3) were prepared. Compound 3 was
successfully employed for the hydrosilylation and hydroboration of
a vast number of ketones. The catalytic performance of 3 in the hydroboration of acetophenone exhibits a turnover frequency,
reaching up to 5800 h–1, outperforming that of reported
zinc hydride catalysts. Notably, both intra- and intermolecular chemoselective
hydrosilylation and hydroboration reactions have been investigated.
创建时间：
2020-08-06
