The Gilded Edge in Acetylenic Scaffolding: Pd-Catalyzed Cross-Coupling Reactions of Phosphine–Gold(I) Oligoynyl Complexes
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https://figshare.com/articles/dataset/The_Gilded_Edge_in_Acetylenic_Scaffolding_Pd_Catalyzed_Cross_Coupling_Reactions_of_Phosphine_Gold_I_Oligoynyl_Complexes/2036661
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资源简介：
Stable bis(gold(I) alkynyl) complexes
of tetraethynylethene (TEE)
derivatives were readily prepared and employed in Sonogashira-like
palladium-catalyzed phosphine–gold(I) halide elimination reactions
with aryl iodides and redox-active tetrathiafulvalene (TTF) mono-
and bisiodides. This presents a particularly convenient method for
the preparation of symmetrical and asymmetrical tetrathiafulvalene
(TTF)-fused radiaannulenes in good yields.
创建时间：
2015-12-17
