A Useful Synthetic Equivalent of a Hydroxyacetone Enolate
收藏NIAID Data Ecosystem2026-03-07 收录
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资源简介：
Indium promoted allylation of carbonyl compounds with 4-(bromomethyl)-1,3-dioxol-2-one diastereoselectively affords anti-α,β-dihydroxyketones, protected as enol carbonates. These initial products can be deprotected to free dihydroxyketones or transformed under mild conditions into the corresponding cyclic carbonates, which constitutes a useful approach to hydroxyacetone aldols.
创建时间：
2011-09-02
