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Synthesis of 2‑Aza-1,3-butadienes through Gold-Catalyzed Intermolecular Ynamide Amination/C–H Functionalization

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https://figshare.com/articles/dataset/Synthesis_of_2_Aza-1_3-butadienes_through_Gold-Catalyzed_Intermolecular_Ynamide_Amination_C_H_Functionalization/3796548
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资源简介:
A novel gold-catalyzed tandem intermolecular ynamide amination/C–H functionalization has been developed. A variety of highly functionalized 2-aza-1,3-butadienes can be obtained readily by utilizing this strategy. In addition, α-imino gold carbene intermediates are proposed in this amination reaction and with support by DFT (density functional theory) calculations.
创建时间:
2016-09-12
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