Design of a Humidity-Stable Metal–Organic Framework Using a Phosphonate Monoester Ligand
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https://figshare.com/articles/dataset/Design_of_a_Humidity_Stable_Metal_Organic_Framework_Using_a_Phosphonate_Monoester_Ligand/2195902
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资源简介：
Phosphonate monoesters are atypical
linkers for metal–organic frameworks, but they offer potentially
added versatility. In this work, a bulky isopropyl ester is used to
direct the topology of a copper(II) network from a dense to an open
framework, CALF-30. CALF-30 shows no adsorption of N2 or
CH4 however, using CO2 sorption, CALF-30 was
found to have a Langmuir surface area of over 300 m2/g
and to be stable to conditions of 90% relative humidity at 353 K owing
to kinetic shielding of the framework by the phosphonate ester.
创建时间：
2016-02-14
