Exploring the fate of Fe(III) at hydrothermal conditions
收藏ESRF Portal2027-01-01 更新2026-04-23 收录
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https://doi.esrf.fr/10.15151/ESRF-ES-1719218822
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资源简介:
Iron is the most abundant redox-active element in many rocks and geofluids. Yet, the redox chemistry of Fe in high temperature geofluids remains controversial. Comprehensive in-situ XAS results suggest that reduction of Fe(III) to Fe(II) occurs around 200 °C, yet thermodynamic modelling and the presence of minerals such as magnetite indicate that Fe(III) exists at higher temperatures. Redox-active materials in autoclaves from previous in-situ experiments may have affected the results; here we plan to use sealed silica capillaries to measure the speciation of iron in saline geofluids at temperatures over 200 °C.
提供机构:
Monash University,Department of Earth Sciences,Clayton Campus,Victoria,VIC 3800 CLAYTON,VIC 3800,CLAYTON,AUSTRALIA; University of Science and Technology Beijing,Geology Department,30 Xueyuan Road, Haidian District, Beijing,100083 BEIJING,CHINA,100083,BEIJING,CHINA; Monash University,School of Earth, Atmosphere & Environment,Rainforest Walk,Clayton Campus,3800 CLAYTON,3800,CLAYTON,AUSTRALIA; Monash University,School of Geosciences, Bldg 28,Wellington Road,Clayton,3800 MELBOURNE,3800,MELBOURNE,AUSTRALIA
创建时间:
2027-01-01



