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Asymmetric Total Synthesis of Dendrobatid Alkaloid 251F

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Asymmetric_Total_Synthesis_of_Dendrobatid_Alkaloid_251F/3644556
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资源简介:
The dendrobatid alkaloid (−)-251F was synthesized. The key steps of the synthesis were (1) an asymmetric Diels−Alder reaction to establish four of the necessary stereocenters in the target, (2) a ring-opening/ring-closing metathesis reaction to establish a key [3.3.0] bicyclic intermediate, and (3) an intramolecular Schmidt reaction.
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2016-08-18
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