Synthesis of <i>Z</i>‑Enamides through Heterogeneous Gold-Catalyzed Stereoselective Hydrogenation of Ynamides
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A facile synthesis of Z-enamides via heterogeneous Au/TiO2 catalyzed stereoselective hydrogenation of ynamides has been developed. Easy to handle and inexpensive ammonium formate was used as the hydrogen source, and Z-enamides were formed in a highly stereoselective manner. The commercially available gold nanoparticle catalyst could be recycled multiple times without a significant loss of activity.
创建时间:
2019-08-06



