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Base-Promoted Tautomerization of Imidazole Ligands to N-Heterocyclic Carbenes and Subsequent Transmetalation Reaction

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NIAID Data Ecosystem2026-03-06 收录
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Imidazole complexes of manganese(I) are transformed into their corresponding N-heterocyclic carbene derivatives by means of acid−base treatments; the subsequent sequential transmetalation reaction of the carbene to gold(I) proceeds through isolable heterometallic intermediate species.

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2007-08-01
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