A Au(I)-Precatalyst with a Cyclopropenium Counterion: An Unusual Ion Pair
收藏Figshare2016-03-14 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Au_I_Precatalyst_with_a_Cyclopropenium_Counterion_An_Unusual_Ion_Pair/2764894
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The synthesis and X-ray crystal structure of a novel Au(I)-precatalyst applied to intermolecular alkyne hydroamination is reported. Density functional theory (DFT) calculations revealed the cyclopropenium counterion of this Au(I)-precatalyst imparts stability through H-bonding and other noncovalent interactions.
创建时间:
2016-03-14



