Total Synthesis of (±)-Gracilioether F
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https://figshare.com/articles/dataset/Total_Synthesis_of_Gracilioether_F/2207053
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Total synthesis of (±)-gracilioether F was achieved via a pivotal reductive cleavage of 1,2-dioxane from allenic ester in 11 steps. The key 1,2-dioxane species, derived from singlet oxygen and a diene, could be used as a common precursor for a stereocontrolled formation of the crucial 1,4-diol through a reductive cleavage.
创建时间:
2016-02-29



