Rhodium(I)-Catalyzed Addition of Arylboronic Acids to (Benzyl-/Arylsulfonyl)acetonitriles: Efficient Synthesis of (Z)-β-Sulfonylvinylamines and β-Keto Sulfones
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Rhodium_I_Catalyzed_Addition_of_Arylboronic_Acids_to_Benzyl_Arylsulfonyl_acetonitriles_Efficient_Synthesis_of_i_Z_i_Sulfonylvinylamines_and_Keto_Sulfones/2697379
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An efficient rhodium(I)-catalyzed addition of arylboronic acids to (benzyl-/arylsulfonyl)acetonitrile is described. Novel β-sulfonylvinylamine products are formed in a stereoselective fashion (Z-alkene). Upon hydrolysis, useful β-keto sulfones are obtained with a broad scope of aryl and sulfonyl substituents.
创建时间：
2016-02-23
