Negative Linear Compressibility of a Metal–Organic Framework
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https://figshare.com/articles/dataset/Negative_Linear_Compressibility_of_a_Metal_Organic_Framework/2502307
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资源简介：
A 3D hybrid zinc formate framework, [NH4][Zn(HCOO)3], possessing an acs topology, shows a high
degree of mechanical anisotropy and negative linear compressibility
(NLC) along its c axis. High-pressure single-crystal
X-ray diffraction studies and density functional theory calculations
indicate that contraction of the Zn–O bonds and tilting of
the formate ligands with increasing pressure induce changes in structure
that result in shrinkage of the a and b axes and the NLC effect along c.
创建时间：
2012-07-25
