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Crystal Structure, Dissolution, and Deposition of a 5 nm Functionalized Metal−Organic Great Rhombicuboctahedron

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https://figshare.com/articles/dataset/Crystal_Structure_Dissolution_and_Deposition_of_a_5_nm_Functionalized_Metal_Organic_Great_Rhombicuboctahedron/3073036
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A metal−organic great rhombicuboctahedron (termed MOP-18) was functionalized with extended alkyl chains and crystallized. It has 12 rigid square-shaped Cu2(CO2)4 paddle-wheel building units and 24 5-dodecoxybenzene-1,3-dicarboxylate links. MOP-18 is soluble in a variety of organic solvents, such as tetrahydrofuran, chloroform, and toluene, which enabled its assembly on graphite substrate and its observation by scanning tunneling microscopy.
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2016-03-01
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