Stable Complexes of Parent Digermene: An Inorganic Analogue of Ethylene
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https://figshare.com/articles/dataset/Stable_Complexes_of_Parent_Digermene_An_Inorganic_Analogue_of_Ethylene/2350555
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资源简介：
The
elusive parent inorganic ethylene H2GeGeH2 has
been isolated in the form of a stable complex for the first
time via donor–acceptor coordination with suitable Lewis base/acid
combinations (LB·H2Ge-GeH2·LA; LB
= N-heterocyclic carbene or N-heterocyclic olefin; LA = W(CO)5). The nature of the bonding in these species was investigated
by density functional theory calculations and revealed the presence
of polarized Ge–Ge covalent σ-bonds within the H2Ge–GeH2 arrays and dative Ge–C interactions
between the digermene and the carbon-based Lewis bases.
创建时间：
2013-11-25
