Structure and Magnetic Properties of the Hybrid System Copper(II) μ<sub>2</sub>-2,2′-Bipyridine-3-carboxylate-<i>N</i>,<i>N</i>′:<i>O</i>-μ<sub>2</sub>-phosphate-<i>O</i>,<i>O</i>′
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The title compound [Cu(PO4H2)(C11H7N2O2)]n presents antiferromagnetic behavior. It has a polymeric one-dimensional structure in which the elemental links are tetranuclear units and the doubly protonated phosphates and the bipyridinemonocarboxylates act in a bridging mode. The magnetic behavior is described using an alternating chain model, with J = −3.32 cm−1, α = 0.7, and g = 2.05.
创建时间:
2016-02-27



