Highly Enantioselective 3-Furylation of Ketones Using (3-Furyl)titanium Nucleophile
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https://figshare.com/articles/dataset/Highly_Enantioselective_3_Furylation_of_Ketones_Using_3_Furyl_titanium_Nucleophile/2803180
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资源简介:
A novel asymmetric 3-furyl addition of (3-furyl)Ti(OiPr)3 to ketones in the presence of 10 mol % (S)-BINOL is reported. The catalytic system works excellently for aromatic ketones, α- or β-halophenones, α,β-unsaturated ketones, and acetylfuran, affording products in high yields with excellent enantioselectivities of up to 97% ee.
创建时间:
2010-01-01



