Lewis Acid Adducts of [PCl<sub>2</sub>N]<sub>3</sub>
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Reaction of aluminum trichloride or gallium trichloride with the extremely weak base hexachlorotriphosphazene gives adducts in which the group 13 element is bound to a phosphazene nitrogen atom. In solution, the adducts exhibit fluxional behavior. The phosphazene ring of the adducts is distorted into a slight chair conformation.
创建时间:
2005-09-19



