A Metallocene-Complexed Dibismuthene: Cp<sub>2</sub>Zr(BiR)<sub>2</sub> (Cp = C<sub>5</sub>H<sub>5</sub>; R = C<sub>6</sub>H<sub>3</sub>-2,6-Mes<sub>2</sub>)
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资源简介：
The zirconocene-complexed dibismuthene, Cp2Zr(BiR)2 (Cp = C5H5; R = C6H3-2,6-Mes2), was prepared by the reaction of sodium metal with Cp2ZrCl2 and RBiCl2. The air- and moisture-sensitive dark reddish/brown compound is the first organometallic compound containing Bi−Zr bonds and the only example of a ZrBi2 ring. Moreover, our computations on associated model systems offer insight into the nature of the interaction of the heaviest dipnictene with a metallocene center.
创建时间：
2005-06-01
