C−C Bond Cleavage of Acetonitrile by a Dinuclear Copper(II) Cryptate
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https://figshare.com/articles/dataset/C_C_Bond_Cleavage_of_Acetonitrile_by_a_Dinuclear_Copper_II_Cryptate/3342070
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资源简介：
The dinuclear copper(II) cryptate [Cu2L](ClO4)4 (1) cleaves the C−C bond of acetonitrile at room temperature to produce a cyanide bridged complex of [Cu2L(CN)](ClO4)3·2CH3CN·4H2O (2). The cleavage mechanism is presented on the basis of the results of the crystal structure of 2, electronic absorption spectra, ESI-MS spectroscopy, and GC spectra of 1, respectively.
创建时间：
2016-05-07
