Heteroligated Metallomacrocycles Generated via the Weak-Link Approach
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
Sequential reaction of two different hemilabile ligands (Ph2PCH2CH2X)2Ar (X = S, Ar = C6H4 or C6(CH3)4; X = NCH3, Ar = C6H4; X = O, Ar = 9,10-C14H8) with a Rh(I) metal center resulted in the formation of heteroligated metallomacrocycles in high yield. The specific reaction conditions for each pair of hemilabile ligands are discussed. The solid-state structure of [{1,4-(Ph2PCH2CH2S)2C6H4}-{1,4-(Ph2PCH2CH2S)2C6(CH3)4}Rh2](BF4)2, as determined by X-ray crystallography, is presented.
创建时间：
2016-05-06
