Chiral Dinuclear Vanadium Complex-Mediated Oxidative Coupling of Resorcinols
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https://figshare.com/articles/dataset/Chiral_Dinuclear_Vanadium_Complex-Mediated_Oxidative_Coupling_of_Resorcinols/7461809
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资源简介:
A method
for the highly regio- and enantioselective oxidative coupling
of resorcinols has been established by using dibrominated dinuclear
vanadium(V) catalyst 1c under air. When resorcinols bearing
an aryl substituent were applied as substrates to the coupling, axially
chiral biresorcinols were obtained as single regioisomers in high
yield with up to 98% ee.
创建时间:
2018-12-13



