Absolute asymmetric synthesis of a homochiral polymer from an achiral monomer
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The present work describes about the absolute asymmetric synthesis of a homochiral polymer from an achiral monomer, via topochemical reactions.Fig 2a: Time-dependent nmr at 70 oCFig 2b: Time-dependent nmr at 100 oCFig 2c: Time-dependent ir at 70 oCFig. 2d: Overlay of solid-state nmr of monomer and polymerFig. 3a: GPC of polymerFig.3b: PXRDFig.3c: Time-dependent PXRD at 70 oCSupplementary Fig.3: Time-dependent nmr at 120 oCSupplementary Fig.5: Overlay of monomer and monomer heated at 90 oCSupplementary Fig.7-11: Monomer nmrSupplementary Fig.16-18: Compound 6 nmr
创建时间:
2025-03-25



