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A Single-Chain Magnet with a Very High Blocking Temperature and a Strong Coercive Field

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NIAID Data Ecosystem2026-03-09 收录
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Two isostructural 1D complexes, [M­(hfac)2NaphNN]n [M = MnII (1) or CoII (2); NaphNN = 1-naphthyl nitronylnitroxide], were synthesized and exhibit very strong antiferromagnetic metal–radical exchange coupling. Compound 2 shows slow magnetic relaxation behavior with a high blocking temperature (TB ≈ 13.2 K) and a very high coercive field of 49 kOe at 4.0 K.

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2016-02-12
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