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The Design, Synthesis and Validation of Recoverable and Readily Reusable Siloxane Transfer Agents for Pd-Catalyzed Cross-Coupling Reactions

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/The_Design_Synthesis_and_Validation_of_Recoverable_and_Readily_Reusable_Siloxane_Transfer_Agents_for_Pd_Catalyzed_Cross_Coupling_Reactions/2414245
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The development of competent, recoverable and reusable 1-oxa-2-silacyclopentene (siloxane) transfer agents for Pd-catalyzed cross-coupling reactions (CCRs) of organolithium reagents with aryl and alkenyl iodides has been achieved. Drawbacks of the first-generation siloxane-transfer agent (1), relating to facile recovery for potential recycling, have been addressed.
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2016-02-19
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