Flash Communication: Synthesis and Reactivity of a Zinc-Bpin Species
收藏NIAID Data Ecosystem2026-05-10 收录
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https://figshare.com/articles/dataset/Flash_Communication_Synthesis_and_Reactivity_of_a_Zinc-Bpin_Species/30773525
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资源简介:
In this work, we report the synthesis
of a NacnacDipp-ligated zinc-Bpin species, compound 3, which
was characterized
by single-crystal X-ray analysis, NMR, and HRMS spectra. Similar to
previously reported zinc-Bcat species, it can also act as a Bpin– nucleophile toward MeI, yielding MeBpin. Furthermore,
it can react with phenyl azide to produce an imide species, which
can be interpreted as the result of phenylnitrene insertion into the
Zn–B bond.
创建时间:
2025-12-02



