Syntheses and Structures of Tetraplatinum Bis(polyynediyl) Complexes with Laterally Arrayed sp Carbon Chains
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https://figshare.com/articles/dataset/Syntheses_and_Structures_of_Tetraplatinum_Bis_polyynediyl_Complexes_with_Laterally_Arrayed_sp_Carbon_Chains/3313372
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资源简介：
Reactions of trans,trans-(C6F5)(p-tol3P)2Pt(C⋮C)nPt(P-p-tol3)2(C6F5) (n = 3, 4) and Ph2P(CH2)3PPh2
(2.5 equiv) give the tetraplatinum complexes (95−81%), in
which two sp carbon chains span two 12-membered-ring
termini. Chain−chain interactions have been probed by
crystallography, UV−visible spectroscopy, cyclic voltammetry, and thermolyses.
创建时间：
2004-12-06
