The Carbanionic Phosphoylide Dianion [PhP(CH<sub>2</sub>)<sub>3</sub>]<sup>2−</sup>, Isoelectronic with Phosphonate Dianions [RP(O)<sub>3</sub>]<sup>2−</sup>
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Deprotonation of [PhP(CH3)3]+[I]− with tBuLi gives [Li2{PhP(CH2)3}·2thf]2 (1), whose [PhP(CH2)3]2− anion is isoelectronic with the phosphonate dianion [RP(O)3]2−.
创建时间:
2016-02-26



