The Synthesis and Metal Coordination Chemistry of a Novel Phosphine- and Thiolate-Substituted Ferrocenediyl Ligand
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https://figshare.com/articles/dataset/The_Synthesis_and_Metal_Coordination_Chemistry_of_a_Novel_Phosphine-_and_Thiolate-Substituted_Ferrocenediyl_Ligand/3767538
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资源简介：
A novel, asymmetric 1,1‘-disubstituted ferrocenediyl ligand featuring phosphine and thiolate substituents has been conveniently synthesized and structurally characterized, and its coordination chemistry was
probed by reaction with late transition metal reagents.
Bridged dimeric species, with the thiolate S adopting a
binucleating role, are observed for Pd(II) and Rh(I) metal
centers, while a mononuclear, square planar Ni(II)
complex is formed on reaction of the ligand with [Ni(TMEDA)Me2].
创建时间：
2016-08-26
