Amino Acid Templating of Inorganic Networks: Synthesis and Structure of l-Asparagine Zinc Phosphite, C<sub>4</sub>N<sub>2</sub>O<sub>3</sub>H<sub>8</sub>·ZnHPO<sub>3</sub>
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C4N2O3H8·ZnHPO3 is the first zincophosphite framework to be templated by an amino acid (l-asparagine), which bonds to Zn via a carboxyl O atom. It contains infinite, homochiral, helical 4-ring chains of ZnO4 and HPO3 groups, stabilized by intra- and interchain N−H···O hydrogen bonds. Crystal data: C4N2O3H8·ZnHPO3, Mr = 277.49, orthorhombic, P212121 (No. 19), a = 5.0349(2) Å, b = 9.4539(4) Å, c = 18.6092(8) Å, V = 885.79 (6) Å3, Z = 4.
创建时间：
2016-05-07
