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The Isopropylsulfinyl Group: A Useful Chiral Controller for the Asymmetric Aziridination of Sulfinylimines and the Organocatalytic Allylation of Hydrazones

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NIAID Data Ecosystem2026-03-06 收录
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A comparative study shows that the isopropylsulfinyl group for which an enantiodivergent and highly diastereoselective approach is reported behaves better than the tert-butylsulfinyl and p-tolylsulfinyl groups, both in terms of reactivity and stereoselectivity in the Corey−Chaykovsky reaction of chiral sulfinylimines and the organocatalytic allylation of acyl hydrazones.

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2016-05-06
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