Acyl Polysilanes: New Acyl Anion Equivalents for Additions to Electron-Deficient Alkenes
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https://figshare.com/articles/dataset/Acyl_Polysilanes_New_Acyl_Anion_Equivalents_for_Additions_to_Electron_Deficient_Alkenes/2846275
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资源简介：
Silenes, generated through thermolysis of acylpolysilanes, add to α,β-unsaturated esters to form cyclobutanes and silylsubstituted cyclopropanes in moderate yields. Upon Si−C bond oxidation the cyclopropanes are converted directly to 1,4-dicarbonyl compounds, thus demonstrating the formal acyl anion chemistry of acyl polysilanes.
创建时间：
2016-02-26
