Acyl Polysilanes: New Acyl Anion Equivalents for Additions to Electron-Deficient Alkenes
收藏NIAID Data Ecosystem2026-03-06 收录
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Silenes, generated through thermolysis of acylpolysilanes, add to α,β-unsaturated esters to form cyclobutanes and silylsubstituted cyclopropanes in moderate yields. Upon Si−C bond oxidation the cyclopropanes are converted directly to 1,4-dicarbonyl compounds, thus demonstrating the formal acyl anion chemistry of acyl polysilanes.
创建时间：
2016-02-26
