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Synthesis of meso-Tetraaryl Triphyrins(2.1.1)

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Figshare2018-09-28 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_i_meso_i_-Tetraaryl_Triphyrins_2_1_1_/7149119
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A simple, straightforward [2+1] condensation of 5,6-diaryldipyrroethene dicarbinols with pyrrole under mild acid-catalyzed conditions resulted in the formation of highly desirable aromatic β-free meso-tetraaryl [14]­triphyrins(2.1.1) in 15–18% yields. The triphyrins(2.1.1) are very novel monoanionic tridentate ligands that form metal complexes readily as demonstrated here by preparing Re­(I) complexes.
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2018-09-28
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