Toward the Synthesis of Phomoidride D
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https://figshare.com/articles/dataset/Toward_the_Synthesis_of_Phomoidride_D/2451004
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资源简介:
An efficient and highly stereoselective approach toward
the phomoidride
family of natural products is described. The carbocyclic core structure
was assembled using a tandem phenolic oxidation/Diels–Alder
cycloaddition and a tandem 5-exo-trig/5-exo-trig radical cyclization
to deliver an isotwistane intermediate that, upon a late-stage xanthate-initiated
Grob fragmentation, furnishes the requisite bicyclo[4.3.1]decene.
创建时间:
2013-01-18



