Iridium-Catalyzed Enantioselective Polyene Cyclization
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https://figshare.com/articles/dataset/Iridium_Catalyzed_Enantioselective_Polyene_Cyclization/2459374
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A highly enantioselective polycyclization method has been developed using the combination of Lewis acid activation with iridium-catalyzed allylic substitution. This strategy relies on direct use of branched, racemic allylic alcohols and furnishes a diverse and unique set of carbo- and heteropolycyclic ring systems in good yields and ≥99% ee.
创建时间：
2016-02-20
