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Comment on “Topological Analysis of the Electron Density in the Carbonyl Complexes M(CO)<sub>8</sub> (M = Ca, Sr, Ba)”

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NIAID Data Ecosystem2026-03-11 收录
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We question the statement of a recent publication (Organometallics 2020, 39, 132, DOI: 10.1021/acs.organomet.9b00699) that the M → CO π backdonation in the alkaline earth carbonyl complexes M­(CO)8 (M = Ca, Sr, Ba) is negligible and that the decrease of the CO stretching frequency is rather caused by interligand interactions of the carbonyl groups within the molecules.

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2020-08-13
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