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Enantioselective Synthesis of Planar-Chiral Metacyclophanes through Rhodium-Catalyzed Alkyne Cyclotrimerization

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_Planar_Chiral_Metacyclophanes_through_Rhodium_Catalyzed_Alkyne_Cyclotrimerization/3027025
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We have achieved the first catalytic enantioselective synthesis of planar-chiral metacyclophanes by means of cationic rhodium(I)/(R)-H8-BINAP complex-catalyzed alkyne cyclotrimerization. This reaction represents a versatile new method for the preparation of planar-chiral [7]−[10]metacyclophanes.
创建时间:
2007-02-14
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