Iodine-Promoted Radical Cyclization in Water: A Selective Reaction of 1,6-Enynes with Sulfonyl Hydrazides
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https://figshare.com/articles/dataset/Iodine_Promoted_Radical_Cyclization_in_Water_A_Selective_Reaction_of_1_6_Enynes_with_Sulfonyl_Hydrazides/2092621
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资源简介：
An iodine-promoted one-pot radical
cyclization reaction of 1,6-enynes
with sulfonyl hydrazides to provide five-membered and hexatomic ring
sulfonylated products under the same conditions is established. This
reaction proceeded smoothly in water and gave the corresponding products
by using I2/TBHP instead of expensive and toxic catalysts
with C–S and C–I bond formed in one step. This method
also allowed easy access to significant functional sulfones for potential
applications in medicinal and organic chemistry.
创建时间：
2016-02-12
