Chlorophosphino Carbyne Complexes of Tungsten
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Chlorophosphino_Carbyne_Complexes_of_Tungsten/3467981
下载链接
链接失效反馈官方服务：
资源简介：
A range of chlorophosphinocarbyne
complexes [W(CPClR)(CO)2(Tp*)] (R = Cl, Cy,
Ph; Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate)
has been prepared by reaction of chlorophosphines with the lithiocarbyne
complex [W{CLi(THF)n}(CO)2(Tp*)]. These complexes undergo nucleophilic substitution
of chloride to enable the preparation of phosphinocarbynes bearing
alkyl, aryl, alkynyl, aryloxy, and secondary phosphino substituents
[W(CPRR′)(CO)2(Tp*)] (R = Ph, R′
= Me, Ph, CCPh, OPh, H; R = Cy, R′ = H).
创建时间：
2016-07-05
