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Syntheses and Structures of the Trinuclear Ruthenium Complexes [RuCl<sub>2</sub>(PAd<sub>2</sub>Bu)]<sub>3</sub> and [RuCl<sub>2</sub>(P<i><sup>t</sup></i><sup></sup>Bu<sub>2</sub>Cy)]<sub>3</sub>

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The trinuclear ruthenium complexes [RuCl2-(PAd2Bu)]3 and [RuCl2(PtBu2Cy)]3 have been obtained by reaction of [(cymene)RuCl2]2 with 2 equiv of the respective phosphine. Crystallographic analyses show that the three metal fragments are connected by strong Ru−Ru bonds and bridging chloro ligands.

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2016-05-05
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