Carboxylative Cyclization of 2‑Butenoates with Carbon Dioxide: Access to Glutaconic Anhydrides
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Cyclic anhydrides are versatile synthons and functional comonomers. Herein, we reported an organic base-promoted carboxylative cyclization of 2-butenoates with carbon dioxide to produce important glutaconic anhydrides in good yields. This metal-free reaction showed broad substrate scopes and proceeded under mild reaction conditions.
创建时间:
2020-08-06



