Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_Trisubstituted_Allenes_via_Cu_I_-Catalyzed_Coupling_of_Diazoalkanes_with_Terminal_Alkynes/4165764
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资源简介：
A highly enantioselective synthesis
of trisubstituted allenes has
been achieved through Cu(I)-catalyzed cross-coupling of aryldiazoalkanes
and terminal alkynes with chiral bisoxazoline ligands. Alkynyl migratory
insertion of Cu(I) carbene is proposed as the key step for the construction
of axial chirality.
创建时间：
2016-11-04
