Synthesis and Characterization of an Unsymmetrical 1,2-Diphosphinoethanide Complex
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_an_Unsymmetrical_1_2_Diphosphinoethanide_Complex/2655151
下载链接
链接失效反馈官方服务：
资源简介：
A palladium 1,2-ethylene-bisphosphine complex prepared by diphosphination of acrylonitrile and subsequent complexation undergoes facile and reversible C deprotonation at a backbone carbon atom. The 1,2-diphosphinoethanide complex that formed was characterized by spectroscopic data and a single-crystal X-ray diffraction study. The reaction may explain the previously observed configurational lability of coordinated 1,2-bisphosphine ligands with electron-withdrawing substituents.
创建时间：
2011-05-09
