Chemical composition of both doors.

Two 11th- and 12th-century entrance doors from the Basilica di San Marco in Venice, made of different copper alloys and woods, were non-invasively examined in situ. The chemical composition of the metals, the way in which different metal parts were joined together, the tree species used to construct the supporting structures and the age of the wood are determined. A portable ED-XRF instrument and optical microscopes were used. The doors were also photographed to produce high-resolution orthophotos and 3D models. The metal parts of the doors were made of leaded tin-bronze and quaternary Cu-Sn-Zn-Pb alloys and were mounted on a wooden multi-layer structure of larch and silver fir; the dendrochronological dates of some of the larch boards are 1965, teminus post quem.