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Boron-Selective Biaryl Coupling Approach to Versatile Dibenzoxaborins and Application to Concise Synthesis of Defucogilvocarcin M

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Boron_Selective_Biaryl_Coupling_Approach_to_Versatile_Dibenzoxaborins_and_Application_to_Concise_Synthesis_of_Defucogilvocarcin_M/2228542
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资源简介:
An efficient synthetic method for versatile dibenzoxaborins based on boron-selective Suzuki–Miyaura cross-coupling between o-borylphenols and aryl halides or triflates bearing a 1,8-diamino­naph­thalene-protected o-boryl group is reported. A short synthesis of defucogilvocarcin M was achieved using the proposed method in combination with several other boron-mediated transformations.
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2014-12-05
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